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OSICO_products_NdYVO4
 
Neodymium doped Yttrium Orthovanadate (Nd:YVO4) Crystal

Shown excellent in efficiency, physical, optical and mechanical properties, Nd:YVO4 crystal is widely applied as laser material to diode-pumped solid-state (DPSS) lasers to yield stableand powerful red, green and infrared laser. In comparison with Nd:YAG material for diode-pumping applications.
Nd:YVO4 lasers have the following features:
• lower lasing threshold and higher slope effciency;
• large stimulated emission cross-section at lasing wavelength;
• high absorption over a wide pumping wavelength bandwidth;
• low dependency on pumping wavelength and easier to yield single mode output.

OSICO manufactures and provides customers with different kinds of dopants and different doping levels of Nd:YVO4 crystals on a competitive pricing basis.

Basic Properties
Atomic Density 1.26x1020 atoms/cm3 (Nd 1.0%)
Crystal Structure zircon tetragonal, space group D4h-I4/amd
a=b=7.1193
Density 4.22g/cm3
Mohs Hardness 4-5 (Glass-like)
Thermal Expansion Coefficient (300K) aa=4.43x10-6/K
ac=11.37x10-6/K
Thermal Conductivity Coefficient (300K) //C: 0.0523W/cm/K
¡Í C: 0.0510W/cm/K

Optical Properties
Lasing wavelength 1064nm, 1342nm
Thermal optical coefficient (300K) dno/dT=8.5x10-6/K
dne/dT=2.9x10-6/K
Stimulated emission cross-section 25x10-19cm2@1064nm
Fluorescent lifetime 90ms
Absorption coefficient 31.4cm-1 @810nm
Intrinsic loss 0.02cm-1 @1064nm
Gain bandwidth 0.96nm @1064nm
Polarized laser emission p polarization; parallel to optic axis(c-axis)
Diode pumped optical to optical efficiency >60%
Sellmeier equations (for pure YVO4 crystals)( ¦Ë in mm )
no2 = 3.77834 + 0.069736/(¦Ë2 –0.04724) – 0.0108133 ¦Ë2
ne2 = 4.59905 + 0.110534/(¦Ë2 –0.04813) – 0.0122676 ¦Ë2

Laser Properties of Nd:YVO4
Laser crystal
Doping(atm%)
s
(x10-19cm2)
a(cm-1)
t (ms)
l a(mm)
Pth(mW)
hs(%)
Nd:YVO4 (a-cut)
1.0
2.0
25
25
31.2
72.4
90
50
0.32
0.14
30
78
52
48.6
Nd:YVO4 (c-cut)
1.1
7
9.2
90
 
231
45.5
Nd:YAG
0.85
6
7.1
230
1.41
115
38.6

Diode pumped Nd:YVO4 laser output comparing with diode pumped Nd:YAG laser
Crystals Size (mm3) Pump Power Output (at 1064nm)
Nd:YVO4 3x3x1 850mW 350mW
Nd:YVO4 3x3x5 15W 6W
Nd:YAG 3x3x2 850mW 34mW

Diode pumped Nd:YVO4+KTP green laser
Nd:YVO4 (mm3) KTP (mm3) Pump Power Output (TEM00 at 532nm)
3x3x1 3x3x5 890mW 76mW
3x3x1 3x3x5 50mW 2.5mW

Typical Nd:YVO4 Crystal Specifications

Transmitting wavefront distortion: less than ¦Ë /4 @ 633 nm
Dimension tolerance: (W ± 0.1mm)x(H ± 0.1mm)x(L ±0.1mm)
Clear aperture: > 90% central area
Flatness: ¦Ë /8@ 633 nm, and ¦Ë /4 @633nm for thickness less than 2mm
Scratch/Dig code: 10/5 to MIL-O-13830A
Parallelism: better than 20 arc seconds
Perpendicularity: 5 arc minutesAngle tolerance: < ± 0.5o
AR coating: R< 0.2% at 1064nm
HR coating: R>99.8% at 1064nm, T>95% at 808nm

 
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